Melanie over at Facekitty have written a good top five list. Grooming Cats: Top Five Tips for a Healthy Coat
I really like the vacuum cleaner idea. I think it also depends on what type of vacuum cleaner you have. A big central one might suck a little to much for the little cat.

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Brushing the cat helps to prevent hair balls and also keeps
the fur fluffy and untangled. When you brush the cat you
can also check the skin for any cuts and bruises. It is also
a good way to check for ticks if you have an outdoor cat.
Some cats just love their brush. They love it so much [...]

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